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Thermodynamics
F+EF+mnrF+mnrBF 2017 . 2018 - 1º semestre
syllabus and bibliography 1 - Fundamental concepts
Thermodynamic systems and variables. Thermodynamic processes and equilibrium. State equation and internal energy equation. 2 - Law zero Temperature. Thermal equilibrium. Thermometers and temperature scales. Fixed points. Kelvin scale. Water triple point. Microscopic concept of temperature. Volume expansion and isothermal compressibility coefficients. 3 - First law Work and heat. Thermal capacities at constant pressure and volume. Enthalpy. Internal energy of perfect gases. Energy equipartition. Heat transfer processes. Phase transitions. 4 - Second law Cyclic heat machines. Carnot cycle. Entropy. Clausius theorem. Reversible and irreversible cycles. Thermodynamic's fundamental relation. Helmholtz and Gibbs functions. Thermodynamic potentials. Maxwell relations. Principles of maximal entropy and minimal internal energy. 5 - Third law Formulations of Nernst and Planck. Bibliography of reference 1. M.W. Zemansky e R.H. Dittman, "Calor e Termodinâmica" Ed. Guanabara Dois, Rio de Janeiro (1978).
2. F.W. Sears e G. L. Salinger, "Termodinâmica, Teoria cinética e Termodinâmica Estatística" Ed. Guanabara Dois, Rio de Janeiro (1978). 3. J. Guémez, C. Fiolhais e M. Fiolhais, "Fundamentos de Termodinâmica do Equilíbrio", Serviço de Educação da Fundação Calouste Gulbenkian (1998), Lisboa.
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